950777-94-3Relevant academic research and scientific papers
Synthesis of 1,2-amino alcohols by sigmatropic rearrangements of 3-(N-Tosylamino)allylic alcohol derivatives
Barbazanges, Marion,Meyer, Christophe,Cossy, Janine,Turner, Peter
, p. 4480 - 4495 (2011/06/24)
Sigmatropic rearrangements of 3-(N-tosylamino)allylic alcohol derivatives, a particular subclass of functionalized enamides, have been investigated. Whereas the presence of the nitrogen atom alters the stereochemical outcome of Ireland-Claisen rearrangeme
Stereoselective synthesis of 1,2-aminoalcohols by [2,3]-wittig rearrangements
Barbazanges, Marion,Meyer, Christophe,Cossy, Janine
, p. 3245 - 3248 (2008/02/12)
[2,3]-Wittig rearrangements of (E)-3-aza-allylic alcohol derivatives can provide access to functionalized 1,2-aminoalcohols with high syn or anti diastereoselectivity depending on the anionic stabilizing group (amide or alkyne). American Chemical Society.
