95080-04-9Relevant academic research and scientific papers
An experimental study of the reactivity of the hydroxide anion in the gas phase at room temperature, and its perturbation by hydration
Tanner, Scott D.,Mackay, Gervase I.,Bohme, Diethard K.
, p. 1615 - 1621 (2007/10/02)
Flowing afterglow measurements are reported which provide rate constants and product identifications at 298 +/-2 K for the gas-phase reactions of OH1- with CH3OH, C2H5OH, CH3OCH3, CH2O, CH3CHO, CH3COCH3, CH2CO, HCOOH, HCOOCH3, CH2=C=CH2, CH3-CCH, and C6H5CH3.The main channels observed were proton transfer and solvatation of the OH-.Hydration with one molecule of H2O was observed either to reduce the rate slightly and lead to products which are the hydrated analogues of the "nude" reaction, or to stop the reaction completely, k 3 molecule-1s-1.The reaction of OH-.H2O with CH3-CCH showed an uncertain intermediate behaviour.
