950891-41-5Relevant academic research and scientific papers
Mechanochemical control of synthesis and structures of aqua-bridged binuclear nickel(II) benzoate complexes
Karmakar, Anirban,Sarma, Rupam J.,Baruah, Jubaraj B.
, p. 4673 - 4678 (2006)
Synthetic and structural aspects of a few binuclear nickel(II) complexes, having two bridging carboxylate groups and aqua groups are reported. Intramolecular O-H...O hydrogen bonding interactions between the bridging aqua group and the monodentate benzoate groups stabilises the bridging structures. Aqua-bridged nickel(II) benzoate complex is stable irrespective of solvent system and also can include solvent molecules such as toluene and benzene. A mixed chloro, aqua and 4-chloro-benzoato-bridged NiII binuclear complex was synthesised and structurally characterised. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.
