95101-83-0Relevant academic research and scientific papers
Sterically Controlled Cu-Catalyzed or Transition-Metal-Free Cross-Coupling of gem-Difluoroalkenes with Tertiary, Secondary, and Primary Alkyl Grignard Reagents
Dai, Wenpeng,Shi, Hongyan,Zhao, Xianghu,Cao, Song
, p. 4284 - 4287 (2016)
A robust copper-catalyzed or transition-metal-free cross-coupling of gem-difluoroalkenes with tertiary, secondary, and primary alkyl Grignard reagents has been developed. Remarkably, the tertiary and secondary alkylation of gem-difluoroalkenes proceeded v
THERMAL ISOMERIZATION OF 2-ARYL-3,3-DIHALOGENO-1,1-DICYCLOPROPYLCYCLOPROPANES
Molchanov, A. P.,Kostikov, R. R.
, p. 1930 - 1935 (2007/10/02)
When heated, 2-aryl-3,3-dihalogen-1,1-dicyclopropylcyclopropanes are converted into 1-aryl-2,6-dihalogeno-3-cyclopropyl-1,3-hexadienes.Electron-donating substituents in the aromatic ring increase and electron-withdrawing substituents decrease the isomeriz
