95112-80-4Relevant academic research and scientific papers
Electrophilic Sulphenylation of Silyl Ketene Acetals Derived from 3-Hydroxyesters. Diastereoselective Synthesis of Protected Epoxyalcohols
Guanti, Giuseppe,Banfi, Luca,Narisano, Enrica,Thea, Sergio
, p. 1683 - 1686 (2007/10/02)
Anti-3-Hydroxy-2-phenylsulphenyl esters are stereoselectively synthesized by reaction between silyl ketene acetals and phenyl sulphenyl chloride.Subsequent elaboration leads to protected epoxyalcohols.
Enantiospecific synthesis of optically pure (3S)-hydroxy esters by the stereocontrolled yeast reduction of α-sulfenyl-β-ketoesters
Fujisawa,Itoh,Sato
, p. 5083 - 5086 (2007/10/02)
Stereocontrol in Baker's yeast reduction of β-ketoesters was successfully achieved by introducing the sulfenyl group at the α-position of the esters to afford optically pure (S)-β-hydroxy esters.
