95119-35-0

Upstream product

• 89690-66-4 ethyl 5,6-dihydro-2-(2-propenyl)-1(2H)-pyridinecarboxylate 
• 95019-44-6 ethyl 5,6-dihydro-2-(3-hydroxypropyl)-1(2H)-pyridinecarboxylate 
• 95019-45-7 ethyl 5,6-dihydro-2-(3-oxopropyl)-1(2H)-pyridinecarboxylate 
• 95044-88-5 ethyl (4β,4aα,7aα)-octahydro-4-hydroxy-5-oxo-1H-1-pyrindinecarboxylate 
• 95019-39-9 ethyl (1aα,1bα,6aα)-1a,1b,3,4,6,6a-hexahydro-6-oxo-2H-oxireno<4.5>cyclopenta<1.2-b>pyridine-2-carboxylate 
• 95019-34-4 ethyl (4aα,7aα,7bα)-4,4a,6,7,7a,7b-hexahydro-1-oxa-2,5-diazacyclopentindene-5(3H)-carboxylate 
• 95019-33-3 ethyl 5,6-dihydro-2-(3-(hydroxyimino)propyl)-1(2H)-pyridinecarboxylate 
• 95019-38-8 ethyl (4β,4aα,5β,7aα)-hexahydro-5-hydroxy-4-(methoxymethoxy)-1H-1-pyrindinecarboxylate 
• 95019-37-7 ethyl (4β,4aα,7aα)-2,3,4,4a,5,7a-hexahydro-4-(methoxymethoxy)-5-oxo-1H-1-pyrindinecarboxylate 
• 95019-46-8 ethyl (1aα,1bα,5β,5aα,6β,6aα)-octahydro-6-hydroxy-5-(methoxymethoxy)-2H-oxireno<4.5>cyclopenta<1.2-b>-pyridine-2-carboxylate 
• 95019-35-5 ethyl (4'β,4'aα,6'α,7'aα)-6'-bromohexahydro-4'-hydroxyspiro<1,3-dioxolane-2,5'-5'H-<1>pyrindine>-1'(2'H)-carboxylate 
• 95019-47-9 ethyl (1aα,1bα,5β,5aα,6aα)-octahydro-5-(methoxymethoxy)-6-oxo-2H-oxireno<4.5>cyclopenta<1.2-b>pyridine-2-carboxylate 
• 127619-59-4 ethyl (4'β,4'aα,6'α,7'aα)-6'-bromohexahydro-4'-(methoxymethoxy)spiro<1,3-dioxolane-2,5'-5'H-<1>pyrindine>-1'(2'H)-carboxylate 
• 95019-36-6 ethyl (4'β,4'aα,7'aα)-3',4',4'a,7'a-tetrahydro-4'-(methoxymethoxy)spiro<1,3-dioxolane-2,5'-5'H-<1>pyrindine>-1'(2'H)-carboxylate 

Relevant academic research and scientific papers

Enantioselective Total Synthesis of Streptazolin. The Tandem Use of Iminium Ion-Vinylsilane Cyclizations and Intramolecular Acylations

The first enantioselective total syntheses of the natural antibiotic (+)-streptazolin (1) and its dihydro derivative 2 are described.Key steps are a stereoselective vinylsilane-terminated cyclization of a tartrate-derived N-acyliminium ion (17 -> 18) and