95124-06-4

Basic information

• Product Name: Cyclohexanemethanol, a-ethenyl-, acetate
• CAS NO: 95124-06-4
• Molecular Formula: C11H18O2
• Molecular Weight: 182.263
• Mol File: 95124-06-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Cyclohexanemethanol, a-ethenyl-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanemethanol, a-ethenyl-, acetate(95124-06-4)
• EPA Substance Registry System: Cyclohexanemethanol, a-ethenyl-, acetate(95124-06-4)

Safety Data

• Hazardous Substances Data: 95124-06-4(Hazardous Substances Data)

Upstream product

• 1826-67-1 vinyl magnesium bromide 
• 108-94-1 cyclohexanone 
• 108-24-7 acetic anhydride 
• 2043-61-0 cyclohexanecarbaldehyde 
• 105880-38-4 (1S)-1-cyclohexyl-2-propyn-1-ol 
• 7560-69-2 1-cyclohexyl-2-propyn-1-one 
• 97563-45-6 1-cyclohexylprop-2-yn-1-ol 
• 108104-21-8 (S)-1-cyclohexyl-2-propyn-1-ol acetate 
• 4352-44-7 1-cyclohexylprop-2-en-1-ol 

Downstream Products

• 95123-99-2 4,4-bis(methoxycarbonyl)-7-cyclohexyl-hept-6(E)-en-1-yne 
• 159009-62-8 (E)-4,4-bis(phenylsulfonyl)-7-cyclohexylhept-6-en-1-yne 
• 108104-23-0 (S)-hexahydromandelaldehyde acetate 
• 37166-70-4 acetic acid 2-cyclohexyl-2-oxoethyl ester 
• 56697-99-5 2-cyclohexyl-2-acetoxyacetaldehyde 
• 61475-31-8 (S)-hexahydromandelic acid 

Relevant articles and documents

Regioselective Asymmetric Allylic Alkylation Reaction of α -Cyanoacetates Catalyzed by a Heterobimetallic Platina-/Palladacycle

Allylic substitution reactions provide a valuable tool for the functionalization of CH acidic pronucleophiles. Often, control over the stereocenter generated at the nucleophilic reactant is still a challenge. The majority of studies that address this issue employ metal complexes with a low metal oxidation state (e.g. Pd0) to form allyl complexes through oxidative addition. In this article we describe the use of heterobimetallic PtII/PdII complexes, which probably activate the olefinic substrates through an SN2′ pathway. The reaction of α-cyanoacetates delivers linear allylation products with exclusive regioselectivity and high E/Z-selectivity for the new C=C double bond. Although the enantioselectivities attained are moderate, they are significantly higher than with related mono-PdII or -PtII catalysts or the corresponding bis-PdII complex, which indicates cooperation of the different metals. Control experiments suggest simultaneous activation of both reaction partners.

A versatile preparation of alpha,beta-unsaturated lactones from homoallylic alcohols.

[formula: see text] A new method for the synthesis of alpha,beta-unsaturated lactones from beta-acetoxy aldehydes by reaction with the lithium enolate of methyl acetate was developed. The reaction is relatively insensitive to structural changes in the ald