951291-08-0Relevant academic research and scientific papers
Na+/K+ switch of enantioselectivity in G-quadruplex DNA-based catalysis
Wang, Changhao,Jia, Guoqing,Li, Yinghao,Zhang, Sufang,Li, Can
, p. 11161 - 11163 (2013)
Here we found that the enantioselectivity of G-quadruplex DNA-based Diels-Alder reaction can be switched by just changing Na+ to K +, which is ascribed to the structural transformation of the G-quadruplex from antiparallel to hybrid-
Ligand denticity controls enantiomeric preference in DNA-based asymmetric catalysis
Boersma, Arnold J.,De Bruin, Bas,Feringa, Ben L.,Roelfes, Gerard
scheme or table, p. 2394 - 2396 (2012/04/10)
DNA-based catalysis can be used to control the enantioselectivity of copper-catalysed Diels-Alder and Friedel-Crafts reactions to produce either enantiomer of the product by changing the denticity of the ligand coordinated to the Cu(ii) ion, even though t
Enantioselective CuII-catalyzed Diels-Alder and Michael addition reactions in water using bio-inspired triazacyclophane-based ligands
Bauke Albada,Rosati, Fiora,Coquiere, David,Roelfes, Gerard,Liskamp, Rob M. J.
experimental part, p. 1714 - 1720 (2011/05/04)
A triazacyclophane (TAC) scaffold decorated with three histidine amino acid residues was used as a tridentate ligand in asymmetric copper(II)-catalysed Diels-Alder and Michael addition reactions in water. Enantiomeric excesses up to 55 % were obtained in
