951308-01-3Relevant academic research and scientific papers
A method of synthesis of natural product Clausenine (by machine translation)
-
, (2017/02/09)
The invention discloses a method of synthesizing a natural product Clausenine and belongs to the field of organic synthesis. The method comprises the steps of reacting 6-diazo-3-methyl-2-cyclohexene-1-ketone with anisidine under the catalysis action of co
Direct amination of phenols under metal-free conditions
Yu, Jianzhong,Wang, Yongtao,Zhang, Peizhi,Wu, Jun
supporting information, p. 1448 - 1454 (2013/07/26)
Herein, we disclose the metal-free synthesis of arylamines via the direct amination of phenols using aminating reagents. This reaction procedure uses easy accessible aminating reagents and provides a versatile synthetic route to a broad range of arylamines with various functionalities in good to excellent yield. By using a two-step route of amination and oxidative coupling reaction, we synthesized three naturally occurring carbazole alkaloids: murrayafoline A, mukonine, and clausenine from two commercially available phenols. Georg Thieme Verlag Stuttgart · New York.
exo-2-oxazolidinone dienes in the total synthesis of the natural carbazoles, 6-methoxymurrayanine and clausenine
Bernal, Pablo,Benavides, Adriana,Bautista, Rafael,Tamariz, Joaquin
, p. 1943 - 1948 (2008/02/10)
A new application of exo-2-oxazolidinone dienes in the regioselective synthesis of natural carbazoles, 6-methoxymurrayanine (6) and clausenine (7), is described. The regioselective cycloaddition of novel diene 10 to acrolein by Lewis acid catalysis provid
