951312-46-2Relevant academic research and scientific papers
Platinum(II) chloride catalyzed cycloisomerizations of 1,5-enynes
Blaszykowski, Christophe,Harrak, Youssef,Brancour, Celia,Nakama, Kimitaka,Dhimane, Anne-Lise,Fensterbank, Louis,Malacria, Max
, p. 2037 - 2049 (2008/02/11)
1,5-Enynes are highly reactive under PtCl2 catalysis and give a range of [3.1.0] bicyclic skeletons. The scope and limitations of this process are presented. Regioisomeric keto derivatives are obtained depending upon the nature of the oxygenate
Preparation of Triesters by Palladium-Catalyzed Vicinal Carbonylation of Substituted-3-methoxycarbonyl-2-propynyl Methyl Carbonates
Mandai, Tadakatsu,Tsujiguchi, Yoshikazu,Matsuoka, Shin,Tsuji, Jiro,Saito, Seiki
, p. 5697 - 5700 (2007/10/02)
The palladium-catalyzed vicinal carbonylation of the 1-substituted-3-methoxycarbonyl-2-propynyl methyl carbonates 6 proceeds at room temperature under atmospheric pressure of CO to give the triesters 7 in good yields.
