951322-69-3Relevant academic research and scientific papers
BISAMINOIMINE LIGAND AND CATALYST HAVING BINAPHTHOL SKELETON
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Paragraph 0034; 0037, (2016/12/26)
PROBLEM TO BE SOLVED: To provide a ligand for supplying a reaction field that is rich in flexibility and is flexible in response to individual reactions and a catalyst using the same. SOLUTION: This invention relates to a ligand represented by formula (1)
Practical asymmetric henry reaction catalyzed by a chiral diamine-Cu(OAc)2 complex
Arai, Takayoshi,Watanabe, Masahiko,Yanagisawa, Akira
, p. 3595 - 3597 (2008/02/12)
The chiral diamine ligand 3 was designed and synthesized from (R,R)-1,2-diphenylethylenediamine, (S)-2,2′-dibromomethyl-1,1′- binaphthalene, and o-xylylene dibromide. The resulting 3-Cu(OAc)2 complex was a highly efficient catalyst for the Henr
