952092-52-3Relevant academic research and scientific papers
An example of overriding cyanation during reaction of a primary alcohol with o-nitrophenyl selenocyanate
Dong, Shuzhi,Paquette, Leo A.
, p. 111 - 114 (2008/02/13)
The first example of a nitrile as the end product of a Mitsunobu substitution involving o-nitrophenyl selenocyanate and tributylphosphine is reported. Neighboring group participation operates and leads favorably to competitive formation of a 2-cyanotetrah
Pestalotiopsin A. Side chain installation and exhaustive probing of olefin metathesis as a possible tool for elaborating the cyclononene ring
Paquette, Leo A.,Dong, Shuzhi,Parker, Gregory D.
, p. 7135 - 7147 (2008/02/11)
(Chemical Equation Presented) A program directed toward an asymmetric synthesis of pestalotiopsin A is described. The routing begins with the dextrorotatory cyclobutanol 37, which is combined with the enantiomerically defined building blocks ent-15 and 16
