952092-72-7Relevant academic research and scientific papers
Pestalotiopsin A. Enantioselective construction of potential building blocks derived from antipodal cyclobutanol intermediates
Paquette, Leo A.,Parker, Gregory D.,Tei, Takahiro,Dong, Shuzhi
, p. 7124 - 7134 (2008/02/11)
(Chemical Equation Presented) D-Glyceraldehyde acetonide has been used as the starting point for accessing the enantiomeric cyclobutanols 11 in optically pure condition. The dextrorotatory enantiomer has been transformed in five steps into the [3.2.0] bic
Pestalotiopsin A. Side chain installation and exhaustive probing of olefin metathesis as a possible tool for elaborating the cyclononene ring
Paquette, Leo A.,Dong, Shuzhi,Parker, Gregory D.
, p. 7135 - 7147 (2008/02/11)
(Chemical Equation Presented) A program directed toward an asymmetric synthesis of pestalotiopsin A is described. The routing begins with the dextrorotatory cyclobutanol 37, which is combined with the enantiomerically defined building blocks ent-15 and 16
