952600-09-8

Basic information

• Product Name: [Cu(6-(4-diethylmethylphosphonatephenyl)-2,2'-bipyridine)(bis(diphenylphosphino)ethane monoxide)]BF₄
• CAS NO: 952600-09-8
• Molecular Weight: 947.173
• Mol File: 952600-09-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Cu(6-(4-diethylmethylphosphonatephenyl)-2,2'-bipyridine)(bis(diphenylphosphino)ethane monoxide)]BF₄(CAS DataBase Reference)
• NIST Chemistry Reference: [Cu(6-(4-diethylmethylphosphonatephenyl)-2,2'-bipyridine)(bis(diphenylphosphino)ethane monoxide)]BF₄(952600-09-8)
• EPA Substance Registry System: [Cu(6-(4-diethylmethylphosphonatephenyl)-2,2'-bipyridine)(bis(diphenylphosphino)ethane monoxide)]BF₄(952600-09-8)

Safety Data

• Hazardous Substances Data: 952600-09-8(Hazardous Substances Data)

Upstream product

• 15418-29-8 tetrakis(acetonitrile)copper(II) tetrafluoroborate 
• 952600-12-3 6-(4-diethylmethylphosphonatephenyl)-2,2'-bipyridine 
• 984-43-0 1,2-bis(diphenylphosphanyl)ethane monoxide 

Relevant articles and documents

Synthesis and structural characterization of two novel copper(I) complexes with oxygen donor

Two novel copper(I) complexes with Cu-O bonds, [Cu2L 2(PPh3)2](BF4)2 (1) and [Cu(L)(dppeo)](BF4) (2) (L = 6-(4-diethylmethylphosphonatephenyl)-2, 2′-bipyridine, dppeo = bis(diphenylphosphino)ethane monoxide), have been prepared and their structures characterized. In the binuclear complex 1, the ligand L serves as tridentate donor with the N, N′ and O as coordination atoms, and the two CuI atoms are bridged through both P = O donor atoms in different ligand L with a triphenylphosphine molecule as auxiliary ligand. While in mononuclear complex 2, both ligands L and dppeo behave as bidentate with N∧N from L and P∧O from dppeo chelating to CuI atom.