952600-29-2Relevant academic research and scientific papers
Novel synthesis of naturally occurring pulvinones: A heck coupling, transesterification, and Dieckmann condensation strategy
Bernier, David,Brueckner, Reinhard
, p. 2249 - 2272 (2008/03/12)
Phosphine-free Heck alkenylations of iodoarenes with trifluoroethyl 2-acetoxyacrylate (19) led stereoselectively to trifluoroethyl (Z)-2-acetoxycinnamates 31-34, 42, 44, and 51. Deacetylation followed by acylation with N,N′-dicyclohexylcarbodiimide activa
Synthesis and cyclization of 3-aryl-2-(arylacetoxy)acrylates: A three-step access to pulvinones
Bernier, David,Moser, Frank,Brueckner, Reinhard
, p. 2240 - 2248 (2008/03/12)
(4-Methoxybenzyl)magnesium chloride was acylated with dialkyl oxalates 14a,b,d or S,S-di-tert-butyl dithiooxalate (14c) to give 2-hydroxy-3-(4- methoxyphenyl)acrylates and -thioacrylates 17a-d. Esterification with phenylacetic anhydride or (4-methoxypheny
