95281-05-3

Basic information

• Product Name: Ethanedione, (2,4-dimethoxyphenyl)(2-hydroxy-4-methoxyphenyl)-
• CAS NO: 95281-05-3
• Molecular Formula: C17H16O6
• Molecular Weight: 316.31
• Mol File: 95281-05-3.mol

Chemical Properties

• CAS DataBase Reference: Ethanedione, (2,4-dimethoxyphenyl)(2-hydroxy-4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanedione, (2,4-dimethoxyphenyl)(2-hydroxy-4-methoxyphenyl)-(95281-05-3)
• EPA Substance Registry System: Ethanedione, (2,4-dimethoxyphenyl)(2-hydroxy-4-methoxyphenyl)-(95281-05-3)

Safety Data

• Hazardous Substances Data: 95281-05-3(Hazardous Substances Data)

Upstream product

• 70779-11-2 1-(2-hydroxy-4 methoxyphenyl)-2-(2,4-dimethoxyphenyl)ethanone 
• 5394-98-9 2,2',4,4'-Tetrahydroxybenzil 
• 77-78-1 dimethyl sulfate 
• 82362-01-4 1,2-bis(2,4-dimethoxyphenyl)ethane-1,2-dione 
• 6706-94-1 2,2'-hydroxy-4,4'-methoxybenzil 

Downstream Products

• 113180-58-8 β-lactone of 2-carboxy-3-hydroxy-2-methyl-2',4',7-trimethoxy-2,3-dihydroisoflavone 
• 113180-54-4 2-{2-[2-(2,4-Dimethoxy-phenyl)-2-oxo-acetyl]-5-methoxy-phenoxy}-propionic acid 
• 103206-86-6 (4,2',4'-trimethoxy-α,α'-dioxo-bibenzyl-2-yloxy)-acetic acid 
• 7678-84-4 3-(2,4-dimethoxyphenyl)-7-methoxy-4H-chromen-4-one 
• 70387-01-8 2-methyl-2',4',7-trimethoxyisoflavone 
• 102591-11-7 2-[3-(2,4-dimethoxy-phenyl)-quinoxalin-2-yl]-5-methoxy-phenol 
• 103508-87-8 (4,2',4'-trimethoxy-α,α'-dioxo-bibenzyl-2-yloxy)-acetic acid ethyl ester 

Relevant articles and documents

Intramolecular Ketene Cycloadditions. Synthesis of Isoflavones and 3-Aroylbenzofurans

The conversion of 2-(carboxyalkoxy)benzils to the corresponding phenoxyketenes to an intramolecular ketene cycloaddition to ultimately yield isoflavones and/or 3-aroylbenzofurans.The ketenes may be generated by the classical dehydrochlorination of the acid chloride or by using Perkin reaction conditions, sodium acetate in refluxing acetic anhydride.The initial cycloaddition products are the corresponding β-lactones, which may decarboxylate to the isolated isoflavones and/or 2-aroylbenzofurans.The product distributions are dependent upon the substitution pattern in the orginal benzil acids.