95307-63-4

Upstream product

• 95307-62-3 α-(4-benzyloxyphenyl)-α-morpholinoacetonitrile 
• 4397-53-9 p-benzyloxybenzaldehyde 

Downstream Products

• 50816-33-6 4-benzyloxybenzaldehyde 
• 1426955-67-0 4-triisopropylsilyloxybenzaldehyde-α-d 
• 1426955-64-7 (S)-(+)-4-triisopropylsilyloxybenzyl-α-d alcohol 
• 50816-34-7 (S)-(+)-4-benzyloxybenzyl-α-d alcohol 
• 1426955-68-1 (R)-(-)-4-triisopropyloxybenzyl-α-d chloride 
• 1426955-69-2 (2S,3S)-N-benzoyl-O-triisopropylsilyl-[3-²H,¹⁵N]-tyrosine (-)-8-phenylmenthyl ester 
• 1426955-71-6 (2S,3S)-N-benzoyl-[3-²H,¹⁵N]-tyrosine (-)-8-phenylmenthyl ester 
• 1426955-73-8 (2S,3S)-[3-²H,¹⁵N]-tyrosine hydrochloride 
• 95307-75-8 (+/-)-4',7-dibenzyloxy<2,3,3-2H3>flavanone 
• 95307-74-7 (+/-)-4',7-dibenzyloxy<2-2H>flavanone 
• 95307-66-7 2',4,4'-trihydroxy<β,3,5-2H3>chalcone 
• 95307-76-9 2',4,4'-trihydroxy<α,β-2H2>chalcone 
• 95307-65-6 4-hydroxybenzaldehyde 
• 95307-64-5 4-hydroxybenzaldehyde 

Relevant academic research and scientific papers

Chirally deuterated benzyl chlorides from benzyl alcohols via hexachloroacetone/polymer-supported triphenylphosphine: Synthesis of protected (2S, 3S)-[3-2H, 15N]-tyrosine

Chirally deuterated benzyl chlorides were prepared using novel, general hexachloroacetone/polymer-supported triphenylphosphine treatment of chirally deuterated benzyl alcohols. Doubly labeled protected tyrosine was obtained in 62% yield with 86% de at the α-carbon and 82% de at the β-carbon. Key in the synthesis was the alkylation of 15N-labeled (-)-8-phenylmenthylhippurate with R-(-)-4-triisopropylsilyloxybenzyl-α-d chloride. Chirally deuterated benzyl chlorides were prepared in high yield with inversion from benzyl alcohols using solid-phase methods. One of the benzyl chlorides obtained was used in the synthesis of protected tyrosine labeled with 15N and chirally deuterated on the β-position. Copyright

Isoflavonoid Biosynthesis: Concerning the Aryl Migration

Feeding experiments with 13C- or 2H-labelled precursors in CuCl2-treated red clover (Trifolium pratense) seedings have demonstrated that the isoflavone formononetin (6) and the pterocarpan phytoalexins medicarpin (10) and maackiain (11) are biosynthesized