95323-73-2Relevant academic research and scientific papers
Formation of 4,6-Dinitro-2-nitrosoaniline by Intramolecular Redox Reaction of Esters and Amides of 2-(2,4,6-Trinitroaniline) Carboxylic Acids
Machacek, Vladimir,Hassanien, Makky M.M.,Sterba, Vojeslav,Lycka, Antonin
, p. 867 - 874 (2007/10/02)
The reaction of methyl and ethyl esters of N-(2,4,6-trinitrophenyl)glycine and N-(2,4,6-trinitrophenyl)-α-alanine (3a-d) with methoxide ion in methanol produces 4,6-dinitro-2-nitrosoaniline (4).N-(2,4,6-Trinitrophenyl)glycine methylamide (1d) gives, under the same conditions, the nitroso compound (4) in addition to 12percent of the spiro adduct (2d).A reaction mechanism is suggested, and the influence of the side chain on the reaction kinetics has been studied.
