95326-09-3Relevant academic research and scientific papers
Ozonolyses of α-Oxo-alkenes: On the Existence of α-Oxo-ozonides
Griesbaum, Karl,Greunig, Hans-Joachim,Volpp, Willi,Jung, In-Chan
, p. 947 - 956 (2007/10/02)
Ozonolyses of nine acyclic (1a-i) and two cyclic (14, 29) α-oxo-alkenes on polyethylene or in pentane afforded in eight cases (1d-i, 14, 29) isolable α-oxo-ozonides. α-Diozonides (9) are obtained from five of the acyclic α-oxo-alkenes (1a, b, d, g, h).All isolated ozonides are labile; the 2,4-dinitrophenylhydrazones of the α-oxo-ozonides, however, are very stable.Decomposition of the α-oxo-ozonides affords not only the hitherto known fragments, but non-peroxidic isomers (8) of the ozonides, too.
