953793-63-0Relevant academic research and scientific papers
Pendant alkenes promote cobalt-cobalt bond cleavage in (alkyne)(binap) tetracarbonyldicobalt(0) complexes
Gibson, Susan E.,Kaufmann, Karina A. C.,Haycock, Peter R.,White, Andrew J. P.,Hardick, David J.,Tozer, Matthew J.
, p. 1578 - 1580 (2008/10/09)
Heating (alkyne)(binap)tetracarbonyldicobalt(0) complexes bearing pendant alkenes leads to cleavage of the cobaltcobalt bond and generation of the mononuclear hydride (binap)(CO)2CoH at 45-55°C.
