95381-68-3Relevant academic research and scientific papers
Triosmium clusters containing diphosphine and triphosphine ligands
Deeming, Antony J.,Donovan-Mtunzi, Susan,Kabir, Shariff E.
, p. 253 - 262 (2007/10/02)
The isomeric butadiene compounds 1,1- and 1,2-and the acetonitrile compound 1,2- react with the diphosphines Ph2P(CH2)nPPh2 (n = 2, 3 or 4) to give separable isomers of Os3(CO
BRIDGING VERSUS CHELATING DIPHOSPHINE IN CLUSTERS: ISOMERS OF Os3(CO)10(DIPHOSPHINE)
Deeming, Antony J.,Donovan-Mtunzi, Susan,Kabir, Shariff E.
, p. C65 - C68 (2007/10/02)
Isomers of Os3(CO)10(diphosphine) (diphosphine = Ph2P(CH2)nPPh2; n = 2 (dppe), n = 3 (dppp), and n = 4 (dppb)) have been prepared in which the diphosphine is chelating (1,1-isomer) or bridging (1,2-isomer), respectively, by displacing butadiene or acetoni
