953814-28-3Relevant academic research and scientific papers
Neutral ligands with exceptional donor ability for palladium-catalyzed alkene hydrogenation
Heckenroth, Marion,Kluser, Evelyne,Neels, Antonia,Albrecht, Martin
, p. 6293 - 6296 (2007)
With four site: Catalytic olefin hydrogenation is observed with palladium complexes when the N-heterocyclic carbene ligand is changed from the normal C2- to the unusual C4-bonding mode (see scheme). In a cis coordinating framework, the electron density at the metal center is substantially increased as a result of the exceptionally strong donor ability of C4-bound carbenes. (Chemical Equation Presented)
Palladation of diimidazolium salts at the C4 position: Access to remarkably electron-rich palladium(ii) centers
Heckenroth, Marion,Kluser, Evelyne,Neels, Antonia,Albrecht, Martin
, p. 6242 - 6249 (2008)
Palladation of C2-protected diimidazolium salts with Pd(OAc)2 afforded complexes comprising C4-bound N-heterocyclic dicarbene ligands. The reactivity of these complexes towards Lewis acids (AgBF4, AgOAc) and Bronsted acids (H2SO4, H3PO4, HOAc) revealed that abnormal C4 bonding of the carbenes markedly increases the nucleophilicity of the coordinated palladium center as compared to C2 bonding. Despite its formal +2 charge, the palladium center in these complexes is best described as a Lewis base. The abnormal carbene bonding mode induces new reaction patterns such as the formation of a Pd-Ag adduct. Based on metallation studies including the palladation of a dissymmetric diimidazolium salt, a rationale for the selective activation of the C4-H bond in the diimidazolium precursor salts is proposed. The Royal Society of Chemistry 2008.
