95384-71-7

Basic information

• Product Name: 5,12-Naphthacenedione, 7,8,9,10-tetrahydro-6,7,8,11-tetrahydroxy-1-methoxy-8-methyl-, trans-
• CAS NO: 95384-71-7
• Molecular Formula: C20H18O7
• Molecular Weight: 370.359
• Mol File: 95384-71-7.mol

Chemical Properties

• CAS DataBase Reference: 5,12-Naphthacenedione, 7,8,9,10-tetrahydro-6,7,8,11-tetrahydroxy-1-methoxy-8-methyl-, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: 5,12-Naphthacenedione, 7,8,9,10-tetrahydro-6,7,8,11-tetrahydroxy-1-methoxy-8-methyl-, trans-(95384-71-7)
• EPA Substance Registry System: 5,12-Naphthacenedione, 7,8,9,10-tetrahydro-6,7,8,11-tetrahydroxy-1-methoxy-8-methyl-, trans-(95384-71-7)

Safety Data

• Hazardous Substances Data: 95384-71-7(Hazardous Substances Data)

Upstream product

• 95384-76-2 rac-7-deoxyfeudomycinone C 

Relevant articles and documents

SYNTHETIC ANTHRACYCLINONES-XXVII. ANTHRACYCLINONES BY INTRAMOLECULAR MARSCHALK REACTION. SYNTHESIS OF THE FEUDOMYCINONES AND RHODOMYCINONES.

1,4,5-Trihydroxy-9,10-anthraquinone is transformed regioselectively to the α-hydroxy dichlorides 18-21, which are cyclized to yield predominantely the naturally configurated 9,10-trans-diols 1,3,26, and 27 (80 to 96percent d.e.).The monotrifluoroacetates 38-40 derived from the trans-diols are hydroxylated via bromination at C-7 to yield almost exclusively the 7,9-cis-9,10-trans-triols α1-rhodomycinone (4), feudomycinone D (7), and 4-O-methyl-β-rhodomycinone (42).The feudomycinones A (5) and C (6) are obtained with less chemo- and stereoselectivity by hydroxylation of the 10-deoxycompounds 33 and 34.