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New Reagents, XXX: Synthesis and Stability of Bis(triphenylplumbyl)methyllithium and Reactions with Alkyl Halides, Carbonyl Compounds, and Oxiranes
Kauffmann, Thomas,Rensing, Alfons
, p. 380 - 390 (2007/10/02)
Bis(triphenylplumbyl)methyllithium (2) is easily accessible by plumbyl-Li or Br-Li exchange from tris(triphenylplumbyl)methane (1b) and bromobis(triphenylplumbyl)methane (3), respectively.Due to its stability and high nucleophilicity 2 is a good reagent for the synthesis of bis(plumbyl)alkanes, -β-hydroxyalkanes, and -γ-hydroxyalkanes.
