954097-62-2Relevant academic research and scientific papers
Expeditious synthesis of contorted hexabenzocoronenes
Plunkett, Kyle N.,Godula, Kamil,Nuckolls, Colin,Tremblay, Noah,Whalley, Adam C.,Xiao, Shengxiong
supporting information; experimental part, p. 2225 - 2228 (2009/10/23)
Contorted hexabenzocoronenes (HBCs) have been synthesized in an expedited manner utilizing a double Barton-Kellogg olefination reaction and a subsequent Scholl cyclization. The scope of both transformations was investigated using a series of pentacene qui
Molecular wires from contorted aromatic compounds
Xiao, Shengxiong,Myers, Matthew,Miao, Qian,Sanaur, Sebastien,Pang, Keliang,Steigerwald, Michael L.,Nuckolls, Colin
, p. 7390 - 7394 (2007/10/03)
(Figure Presented) In a twist: A design strategy for molecule-based electronic materials using aromatic compounds with a nonplanar core is presented. A new class of hexabenzocoronene is put forth that has its core severely distorted out of planarity into a corrugated structure. When substituted with four alkoxy side chains, this material self-assembles into infinitely long columns through stacking (see picture) and acts as an active layer in field-effect transistors.
