95421-01-5

Usage

Uses

Used in Organic Synthesis:
[(2,3,4,5-Tetramethyl-2,4-cyclopentadien-1-yl)methyl]benzene is used as an intermediate in organic synthesis for the production of various chemical compounds. Its unique structure allows for further functionalization and modification, making it a valuable building block in the synthesis of complex organic molecules.
Used in Chemical Research:
[(2,3,4,5-TETRAMETHYL-2,4-CYCLOPENTADIEN-1-YL)METHYL]BENZENE is also utilized in chemical research as a model system for studying the properties and reactivity of cyclopentadienyl derivatives. It helps researchers understand the behavior of similar compounds and develop new synthetic strategies and applications.
Used in Industrial Applications:
[(2,3,4,5-Tetramethyl-2,4-cyclopentadien-1-yl)methyl]benzene finds a range of practical uses in the industry, including its role as a precursor in the production of specialty chemicals, pharmaceuticals, and materials with specific properties.
Used in Pharmaceutical Development:
In the pharmaceutical industry, [(2,3,4,5-Tetramethyl-2,4-cyclopentadien-1-yl)methyl]benzene may be used as a starting material for the development of new drugs, taking advantage of its unique chemical structure and reactivity.
It is important to handle and store this chemical with care, as exposure to high temperatures or open flames can lead to hazardous conditions. Overall, [(2,3,4,5-Tetramethyl-2,4-cyclopentadien-1-yl)methyl]benzene is a significant compound in the field of organic chemistry and has a range of practical uses in industry.

Upstream product

• 13294-71-8 2-bromo-but-2-ene 
• 101-97-3 Ethyl 2-phenylethanoate 
• 54458-61-6 2,3,4,5-tetramethyl-2-cyclopenten-1-one 
• 6921-34-2 benzylmagnesium chloride 
• 1589-82-8 phenylmagnesium bromide 

Relevant academic research and scientific papers

Rapid Access to Derivatized, Dimeric, Ring-Substituted Dichloro(cyclopentadienyl)rhodium(III) and Iridium(III) Complexes

The present work describes the design and synthesis of a series of rhodium and iridium dimers [(η5-ring)MCl]2(μ2-Cl)2 (where (η5-ring)MCl = (η5-Me4C5R)Rh(III)Cl or (η

Extending the range of pentasubstituted cyclopentadienyl compounds: The synthesis of a series of tetramethyl(alkyl or aryl)cyclopentadienes (Cp?R), their iridium complexes and their catalytic activity for asymmetric transfer hydrogen

Tetramethyl(alky or aryl)cyclopentadienes were synthesized and the organometallic half-sandwich iridium complexes of the form [(η5-Cp?R)Ir(aa)Cl], Cp?R = tetramethyl(phenyl)cyclopentadienyl (Cp?

Relative Importance of Dissociative Loss of Carbon Monoxide and Formation of Benzyl Radicals from Photoexcitation of (η5-C5R5)Fe(CO)2(η1-CH2C6H5) and Evidence for Reaction of Carbon Monoxide with 17-Electron Radicals

Near-UV irradiation of (η5-C5R5)Fe(CO)2(η1-CH2C6H5) (R=H, Me) yields both loss of CO and CH2C6H5 radicals as primary photoprocesses, though the loss of CO dominates the excited-state chemistry.At 77 K in a rigid alkane matrix the only detectable photoreaction is loss of CO to form (η5-C5R5)Fe(CO)(η3-CH2C6H5).In fluid alkane solution at 298 K the dominant metal-containing photoproduct is (η5-C5R5)2Fe2(CO)4, unless the solution is actively purged with a stream of an inert gas such as Ar or N2.When the solution is purged with Ar there are two main products: (η5-C5R5)Fe(CO)(η3-CH2C6H5) (90-95percent) and (η5-C5R5)2Fe2(CO)4 (5-10percent).The 366-nm quantum efficiency for CO loss is ca. 0.5, and that for CH2C6H5 loss is ca. 0.05.When (η5-C5R5)Fe(CO)2(η1-CH2C6H5) is irradiated under 2 atm of CO in alkane solution at 298 K (η4-C5R5(CH2C6H5))Fe(CO)3 is formed in good chemical yield (>50percent).X-ray crystallography establishes (η4-C5Me5(CH2C6H5))Fe(CO)3 to have the CH2C6H5 group in an exo position.The formation of (η4-C5R5(CH2C6H5))Fe(CO)3 occurs via light-induced loss of a CH2C6H5 radical from (η5-C5R5)Fe(CO)2(η1-CH2C6H5) followed by reaction of (η5-C5R5)Fe(CO)2 with CO to form (C5R5)Fe(CO)3 that then couples with a CH2C6H5 radical to give the exo isomer of (η4-C5R5(CH2C6H5))Fe(CO)3.