95447-89-5Relevant academic research and scientific papers
Synthesis and Reactions of Selenoketones
Ishii, Akihiko,Okazaki, Renji,Inamoto, Naoki
, p. 861 - 868 (2007/10/02)
A new, convenient method for the synthesis of selenoketones has been reported.The reaction of dimagnesium salts of ketone hydrazones with diselenium dichloride affords an intermediate tentatively assigned as tetraselenides, which are converted into seleno
SELONES AS INTERMEDIATES IN THE PREPARATION OF EXTREMELY STERICALLY HINDERED MOLECULES
Guziec, Frank S.,Sanfilippo, Lynn James,Murphy, Christopher J.,Moustakis, Christine A.,Cullen, Edward R.
, p. 4843 - 4852 (2007/10/02)
The preparation and reactions of selones, selenium analogues of ketones, are described with particular emphasis on their utility in the preparation of extremely sterically hindered molecules.Mechanistic questions related to these reactions are discussed and evidence for "active selenium" is presented.Selenophilic additions of organometallic compounds to selones are also reported.
REACTIONS OF 1,1,3,3-TETRAMETHYLINDANE-2-SELONE WITH GRIGNARD AND ORGANOLITHIUM REAGENTS
Okazaki, Renji,Ishii, Akihiko,Inamoto, Naoki
, p. 5147 - 5150 (2007/10/02)
The title reaction afforded selenophilic, carbophilic, and reduction products depending on the kinds of the organometallic reagents and the heterophilic nature of the reaction was more conspicuous in the reaction with the selenoketone than with the corres
