95448-27-4Relevant academic research and scientific papers
Photo-allylation and photo-benzylation of carbonyl compounds using organotrifluoroborate reagents
Nishigaichi, Yutaka,Orimi, Takayuki,Takuwa, Akio
experimental part, p. 3837 - 3839 (2010/03/04)
Allyl- and benzyl-trifluoroborates can be applied to the photoreaction of carbonyl compounds to afford the corresponding alcoholic adducts in acceptable yields via a photo-induced single electron transfer pathway. The results were confirmed from the react
Regioreversed Allylation in Lewis Acid-mediated and Photochemical Addition Reactions of Unsymmetric α-Diketones with Allylic Stannanes
Takuwa, Akio,Nishigaichi, Yutaka,Yamashita, Koichi,Iwamoto, Hidetoshi
, p. 1761 - 1764 (2007/10/02)
In the photochemical reaction of allyl- and benzyltrimethylstannanes with unsymmetric α-diketones (PhCOCOR), the allylic group was introduced to the benzoyl carbon in high or excellent selectivity, whereas the acyl carbon was allylated either exclusively
