95456-74-9Relevant academic research and scientific papers
Application of a New Reaction of α-Phenylselenylketones to the Synthesis of Erysotrine
Tsuda, Yoshisuke,Hosoi, Shinzo,Nakai, Akira,Ohshima, Takeshi,Sakai, Yuki,Kiuchi, Fumiyuki
, p. 1216 - 1217 (1984)
Treatment of an α-phenylselenylketone with mercury(II) perchlorate in methanol yielded an α,α-dimethoxyketone; by using this new reaction an erythrinan alkaloid, erysotrine, was synthesized.
Synthesis of Erythrina and related alkaloids. XXIV. Total synthesis of erysotrine from 1,7-cycloerythrinan derivatives by the use of a new 1,2-carbonyl transposition method
Tsuda,Hosoi,Nakai,Sakai,Abe,Ishi,Kiuchi,Sano
, p. 1365 - 1373 (2007/10/02)
Treatment of 2,8-dioxo-1,7-cycloerythrinans with phenylselenenyl chloride in the presence of BF3·Et2O as a catalyst gave 3-chloro-3-phenylselenenyl derivatives through the 3-phenylselenenyl derivative, which changed into the Δ3
