95461-17-9Relevant academic research and scientific papers
DEHALOGENATION OF ETHYL 2,5-DICHLORO-3-THIENYLGLYOXYLATE IN THE PRESENCE OF SUPPORTED PALADIUM COMPLEXES
Gurovets, A. S.,Sharf, V. Z.,Taits, S. Z.,Vol'kenshtein, Yu. B.,Fabrichnyi, B. P.
, p. 1331 - 1336 (2007/10/02)
The dependence of the rate and selectivity of the catalytic hydrodehaligenation of ethyl 2,5-dichloro-3-thienylglyoxylate over immobilized palladium complexes on the nature of the solvent and HCl has been investigated.Hydrogenation of the C=O group also occurs.Reductive dechlorination of methyl and ethyl 2,5-dichloro-3-thienylacetates occurs selectively, at a slower rate than in the case of the 3-thienylglyoxylate.
