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• 3085-54-9 N-(4-methylphenyl)formamide 
• 103-89-9 4-Methylacetanilide 
• 612-29-3 o-nitronitrosobenzene 
• 88-74-4 2-nitro-aniline 
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• 1493-27-2 ortho-nitrofluorobenzene 
• 35527-27-6 4’-methyl-2-nitroazobenzene 

Relevant academic research and scientific papers

Selective and Scalable Electrosynthesis of 2H-2-(Aryl)-benzo[d]-1,2,3-triazoles and Their N-Oxides by Using Leaded Bronze Cathodes

Electrosynthesis of 2H-2-(aryl)benzo[d]-1,2,3-triazoles and their N-oxides from 2-nitroazobenzene derivatives is reported. The electrolysis is conducted in a very simple undivided cell under constant current conditions with a leaded bronze cathode and a g

Electroluminescent Metal Complexes With Triazoles And Benzotriazoles

This invention relates to electroluminescent metal complexes with triazoles and benzotriazoles, respectively of the formula (I) a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especia

Vergleichende Untersuchungen zur Arylaminierung von Benzofuroxan-Derivaten

The amination of benzofuroxan 2a and monosubstituted benzofuroxans 2b-e with alkali metal salts of formanilides 1 and sodium acetanilides 6 is described.Thus, the reaction of 2a with 6a-d gives the benzotriazole 1-oxides 3a-d.The benzofuroxans 2b and 2c react with sodium formanilides to give the isomeric mixtures 3f/3g and 3h/3i.Potassium 4-nitroformanilide reduces 2a furnishing benzofurazan 7.Nitrosubstituted benzofuroxans such as 2d and 2e undergo a carbocyclic amination leading to the benzofurazans 8 and 9.

A NOVEL SYNTHETIC ROUTE TO 2-ARYL-2H-BENZOTRIAZOLE 1-OXIDES

The reaction of benzofuroxan 1 with sodium or potassium salts of formanilides 2 affords 2-aryl-2H-benzotriazole 1-oxides 3 in moderate to good yields.By heating the reactants in toluene or DMSO formal O/N exchange with elimination of alkali formate takes

The Reduction of Some o-Nitrophenylazo Dyes with Thiourea S,S-Dioxide (Formamidinesulfinic Acid): a General Synthesis of 2-Aryl-2H-benzotriazoles and Their 1-Oxides

Thiourea S,S-dioxide (formamidinesulfinic acid) reacts with o-nitrophenylazo dyes in ethanolic alkali to give, depending on the reaction conditions, either the corresponding 2-aryl-2H-benzotriazoles or their 1-oxides.The reagent is particularly effective for preparing in high yield 2-(2'H-benzotriazol-2'-yl)phenols, which are important ultraviolet absorbers.The corresponding reductions involving ammonium sulfide and sodium dithionite were also examined.The former reagent was unsatisfactory; the latter reagent behaved erratically and was a less effective reducing reagent than thiourea dioxide.Nevertheless, conditions were established whereby sodium dithionite furnished the 2-(2'H-benzotriazol-2'-yl)phenols in high yield and purity.