95482-77-2Relevant academic research and scientific papers
Asymmetric diels-alder reactions of sulfonyl-functionalized α,β-unsaturated ketones with cyclopentadiene catalyzed by chiral lewis acid
Pei, Wen,Wang, Yu-Guang,Wang, Yong-Jiang,Sun, Li
experimental part, p. 3383 - 3388 (2009/05/07)
Asymmetric Diels-Alder reactions of (E)-1-substituted sulfonyl-3-penten-2- ones with cyclopentadiene catalyzed by a chiral titanium reagent were investigated. The enantioselectivity was studied with different substituents in the position of sulfonyl moiet
STEREOSPECIFIC HYDROXYLATION OF CHIRAL ALLYLIC β-HYDROXYSULFOXIDES: APPLICATIONS TO THE ASYMMETRIC SYNTHESIS OF OPTICALLY ACTIVE VICINAL TRIOLS
Solladie, Guy,Frechou, Catherine,Demailly, Gilles
, p. 2867 - 2870 (2007/10/02)
Chiral allylic β-hydroxysulfoxides 2 have been hydroxylated by the osmium tetroxide catalyzed reaction.The reaction can be highly stereoselective depending on the nature of the substituent linked to the double bond and the configurations of the sulfoxide
