955030-34-9Relevant academic research and scientific papers
Iridium-catalyzed allylation of chiral β-stereogenic alcohols: Bypassing discrete formation of epimerizable aldehydes
Schmitt, Daniel C.,Dechert-Schmitt, Anne-Marie R.,Krische, Michael J.
supporting information, p. 6302 - 6305 (2013/02/25)
The cyclometalated π-allyliridium 3,4-dinitro-C,O-benzoate complex modified by (R)- or (S)-Cl,MeO-BIPHEP promotes the transfer hydrogenative coupling of allyl acetate to β-stereogenic alcohols with good to excellent levels of catalyst-directed diastereose
A cross-metathesis approach for the synthesis of tedanolide and 13-deoxytedanolide: stereoselective synthesis of the C3-C16 segment
Nyavanandi, Vijay Kumar,Nadipalli, Prabhakar,Nanduri, Srinivas,Naidu, Andra,Iqbal, Javed
, p. 6905 - 6911 (2008/02/13)
A unified synthetic strategy has been devised for the synthesis of both tedanolide and 13-deoxytedanolide, which involves a cross-metathesis reaction as the key step. We report herein the stereoselective synthesis of the C3-C16 segment (+)-5b and subseque
Stereoselective Aldol-Type Cyclization Reaction Mediated by Dibutylboron Triflate/Diisopropylethylamine
Das, Sanjib,Li, Lian-Sheng,Sinha, Subhash C.
, p. 123 - 126 (2007/10/03)
(Equation presented) Dibutylboron triflate/diisopropylethylamine mediated aldol-type cyclization provides an expedient route for the stereoselective synthesis of cyclic ethers in a single step. The method is highly efficient for the stereoselective synthe
