955044-65-2Relevant academic research and scientific papers
Cross-coupling reactions between C(sp2)-H and C(sp 3)-H bonds via sequential dehydrogenation and C-H insertion
Kuninobu, Yoichiro,Asanoma, Daisuke,Takai, Kazuhiko
experimental part, p. 2883 - 2886 (2011/02/23)
Formal C(sp2)-H and C(sp3)-H cross-coupling reactions were carried out by iridium-catalyzed transfer dehydrogenation of primary alcohols and sequential manganese-catalyzed insertion of the formed aldehydes into a carbon-hydrogen bond of aromatic or olefinic compounds. Georg Thieme Verlag Stuttgart - New York.
Manganese-catalyzed insertion of aldehydes into a C-H bond
Kuninobu, Yoichiro,Nishina, Yuta,Takeuchi, Takahiro,Takai, Kazuhiko
, p. 6518 - 6520 (2008/09/16)
(Chemical Equation Presented) Mn gets in the game: In the presence of a manganese catalyst and a stoichiometric amount of hydrosilane, aldehydes insert into C-H bonds of aromatic rings of compounds with directing groups (see scheme). This first example of a manganese-catalyzed chemical transformation through C-H bond activation gives silyl ethers in good to excellent yields and can also be applied to asymmetric transformation.
