955044-68-5Relevant academic research and scientific papers
Manganese-catalyzed insertion of aldehydes into a C-H bond
Kuninobu, Yoichiro,Nishina, Yuta,Takeuchi, Takahiro,Takai, Kazuhiko
, p. 6518 - 6520 (2007)
(Chemical Equation Presented) Mn gets in the game: In the presence of a manganese catalyst and a stoichiometric amount of hydrosilane, aldehydes insert into C-H bonds of aromatic rings of compounds with directing groups (see scheme). This first example of a manganese-catalyzed chemical transformation through C-H bond activation gives silyl ethers in good to excellent yields and can also be applied to asymmetric transformation.
