955375-00-5Relevant articles and documents
New chiral ferrocene-bridged phosphole-phosphane ligands
Cortes, Jose Guadalupe Lopez,Ramon, Olivier,Vincendeau, Sandrine,Serra, Daniel,Lamy, Franck,Daran, Jean-Claude,Manoury, Eric,Gouygou, Maryse
, p. 5148 - 5157 (2006)
A convenient synthesis of new chiral ferrocenene-bridged phosphole-phosphane ligands in an enantiomerically pure form has been developed. These new chiral P,P ligands have been tested in a palladium-catalysed allylic substitution reaction. High activities and moderate enantioselectivities (up to 61 %) were observed. A palladium(II) complex has been isolated and its crystal structure established. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.