955378-58-2Relevant academic research and scientific papers
Elucidation of nonstatistical dynamic effects in the cyclization of enyne allenes by means of kinetic isotope effects
Schmittel, Michael,Vavilala, Chandrasekhar,Jaquet, Ralph
, p. 6911 - 6914 (2008/09/18)
In no man's land - a reaction without a classic mechanism: A series of enyne allenes follow neither the classical concerted nor stepwise mechanism but rather comply with dynamic nonstatistical laws. The computed potential energy surface (see figure) and e
