95541-00-7Relevant academic research and scientific papers
AN EFFICIENT SYNTHESIS OF α-F-ALKYNYLATED ALCOHOLS BY NEW SILOXANE-FLUORIDE ION CATALYZED REACTION OF 1H-F-1-ALKENEPHOSPHONATES WITH ALDEHYDES
Ishihara, Takashi,Maekawa, Takashige,Ando, Teiichi
, p. 357 - 360 (2007/10/02)
1H-F-1-Alkenephosphonates react smoothly with a variety of aldehydes under the influence of catalytic amounts of hexamethyldisiloxane and tetrabutylammonium fluoride at room temperature to afford the corresponding α-F-alkynylated alcohols in good to excel
NEW FLUORIDE ION-CATALYZED REACTION OF F-ALKYLACETYLENES WITH SILYL ENOL ETHERS. AN EFFICIENT ROUTE TO F-ALKYL-SUBSTITUTED PROPAPGYLIC ALCOHOLS AND α-HYDROXY KETONES
Ishihara, Takashi,Yamasaki, Yasuhiro,Ando, Teiichi
, p. 79 - 82 (2007/10/02)
Treatment of F-alkylacetylenes, generated in situ from 1H-F-1-alkenephosphonates, with silyl enol ethers in the presence of a catalytic amount of tetrabutylammonium fluoride gives good yields of F-alkyl-substituted propargyl alcohols or 4-(1H-F-alkylidene)-1,3-dioxolane derivatives, the latter being converted to the corresponding α-hydroxy ketones.
