95548-87-1Relevant academic research and scientific papers
Reactions of β-Dicarbonyl Compounds with Acyl Cyanides Catalyzed or Promoted by Metal Centres in the Homogeneous Phase
Veronese, Augusto C.,Callegari, Rosella,Basato, Marino,Valle, Giovanni
, p. 1779 - 1786 (2007/10/02)
The C-C bond-forming reaction between β-dicarbonyl compouds and acyl cyanides is catalyzed by nickel acetylacetonate or promoted by tin tetrachloride.Thus, β-diketones react with acyl cyanides in the presence of catalytic amounts of to give β-
Tin(IV) chloride-promoted versus Metal β-carbonylenolate-catalysed Reactions of β-Dicarbonyls with Nitriles
Veronese, A. C.,Gandolfi, V.,Basato, M.,Corain, B.
, p. 1843 - 1870 (2007/10/02)
β-Ketoesters (2) and β-diesters (3) react with electrophilically activated nitriles, such as trichloroacetonitrile, ethyl cyanoformate and benzoyl cyanide and with non activated nitriles, such as acetonitrile, propiononitrile, benzyl cyanide, benzonitrile
Metal- catalysed Addition of β-Dicarbonyl Compounds to the Nitrile Carbon of Benzoyl Cyanide. Synthesis of 1-Amino-1-benzoyl-2,2-diacylethenes
Basato, Marino,Corain, Benedetto,Cofler, Marino,Veronese, Augusto C.,Zanotti, Guiseppe
, p. 1593 - 1594 (2007/10/02)
The complex (Hacac=pentane-2,4-dione) selectively catalyses addition of the intercarbonylic carbon atom of β-diketones to the cyano group of benzoyl cyanide, whereas usual basic organic catalysts lead to attack on the carbonyl carbon atom with
