95586-10-0Relevant articles and documents
Synthetic studies directed toward ergot alkaloids, (±)-6,7-secoagroclavine, (±)-chanoclavine-1, (±)-chanoclavine-II, and (±)-agroclavine-I, by an efficient and common synthetic route
Yamada, Fumio,Makita, Yoshihiko,Somei, Masanori
, p. 599 - 620 (2008/03/12)
Novel three synthetic routes to (±)-6,7-secoagroclavine were developed from either methyl 3-(3-formylindol-4-yl)acrylate, indole-4-carbaldehyde, or 4-iodoindole-3-carbaldehyde. The total syntheses of (±)-chanoclavine-I, (±)-chanoclavine-II, and (±)-agroclavine-I were accomplished as well from the synthetic intermediates involved in the synthesis of (±)-6,7-secoagroclavine, culminating in establishing an efficient and common synthetic method for ergot alkaloids.
TOTAL SYNTHESES OF (+/-)-AGROCLAVINE-I, (+/-)-6-NOR-CHANOCLAVINE-II, AND (+/-)-CHANOCLAVINE-II
Somei, Masanori,Yamada, Fumio,Makita, Yoshihiko
, p. 895 - 898 (2007/10/02)
The first total syntheses of (+/-)-6-nor-chanoclavine-II and (+/-)-chanoclavine-II are achieved.Total synthesis of (+/-)-agroclavine-I is also reported.
Lewis Acid Assisted Condensations between a 5-Methoxyisoxazolidine and Silicon-Based Nucleophiles: γ-Amino Alcohol Building Block in the Synthesis of Agroclavine I
Kozikowski, Alan P.,Stein, Philip D.
, p. 2569 - 2571 (2007/10/02)
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