955942-03-7

Basic information

• Product Name: (R_S,S)-N-[(1-phenylsulfonyl-1H-4-nitro-indol-2-yl)(p-chlorophenyl)methyl]-tert-butanesulfinylamide
• Synonyms: (R_S,S)-N-[(1-phenylsulfonyl-1H-4-nitro-indol-2-yl)(p-chlorophenyl)methyl]-tert-butanesulfinylamide
• CAS NO: 955942-03-7
• Molecular Weight: 546.068
• Mol File: 955942-03-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R_S,S)-N-[(1-phenylsulfonyl-1H-4-nitro-indol-2-yl)(p-chlorophenyl)methyl]-tert-butanesulfinylamide(CAS DataBase Reference)
• NIST Chemistry Reference: (R_S,S)-N-[(1-phenylsulfonyl-1H-4-nitro-indol-2-yl)(p-chlorophenyl)methyl]-tert-butanesulfinylamide(955942-03-7)
• EPA Substance Registry System: (R_S,S)-N-[(1-phenylsulfonyl-1H-4-nitro-indol-2-yl)(p-chlorophenyl)methyl]-tert-butanesulfinylamide(955942-03-7)

Safety Data

• Hazardous Substances Data: 955942-03-7(Hazardous Substances Data)

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 850655-62-8 4-nitro-1-(phenylsulfonyl)-1H-indole 
• 336105-23-8 (R)-(-)-N-[(1E)-(4-chlorophenyl)methylene]-2-methyl-2-propanesulfinamide 

Relevant articles and documents

Highly diastereoselective reactions of 2-lithiated indoles with chiral N-tert-butanesulfinyl aldimines for the synthesis of chiral (2-indolyl) methanamine derivatives

Nucleophilic addition reactions of 2-lithiated N-phenylsulfonylindoles with (R)-N-tert-butanesulfinyl aldimines provided chiral (2-indolyl) methanamine derivatives in moderate to good yields (up to 100%) with excellent diastereoselectivities (>99:1), in which no additional Lewis acids were required.