955959-40-7

Upstream product

• 955959-41-8 (R,E)-dimethyl 3-((R)-4-(benzyloxy)-3-methylbutylidene)-1,4-dimethyl-5-oxopyrrolidine-2,2-dicarboxylate 
• 1332721-92-2 C₁₆H₂₀O₃ 
• 1332721-77-3 dimethyl 2-((2R,6R)-7-(benzyloxy)-N,2,6-trimethylhept-3-ynamido)malonate 
• 955959-44-1 ((2R,6R)-7-benzyloxy)-2,6-dimethylhept-3-yn-1-ol 

Downstream Products

• 955959-57-6 C₂₀H₂₅NO₇ 
• 1332721-93-3 (3R,3aS,4S,6aS)-4-((R)-3-(benzyloxy)-2-methylpropyl)-dihydro-3a-hydroxy-6a-((methoxymethoxy)methyl)-1,3-dimethyl-1H-furo[3,4-b]pyrrole-2,6(3H,6aH)-dione 
• 1332721-83-1 C₃₇H₆₅NO₈Si₂ 
• 1332721-82-0 (2S,3S,4R)-(triisopropylsilyloxy)methyl 3-((1S,3R)-3-((benzyloxy)methyl)-1-methoxybutyl)-3-hydroxy-2-(hydroxymethyl)-1,4-dimethyl-5-oxopyrrolidine-2-carboxylate 
• 1332721-81-9 C₂₁H₃₁NO₇ 
• 1332721-80-8 C₂₃H₃₅NO₈ 
• 1332721-94-4 (3R,4S,5S)-4-((1S,3R)-4-(benzyloxy)-1-methoxy-3-methylbutyl)-4-hydroxy-5-(hydroxymethyl)-5-((methoxymethoxy)methyl)-1,3-dimethylpyrrolidin-2-one 
• 955959-48-5 (3R,3aS,4S,6aS)-4-((R)-3-(benzyloxy)-2-methylpropyl)-dihydro-3a-hydroxy-6a-(hydroxymethyl)-1,3-dimethyl-1H-furo[3,4-b]pyrrole-2,6(3H,6aH)-dione 

Relevant academic research and scientific papers

Total synthesis of Oxazolomycin a

The first total synthesis of oxazolomycin A, a structurally novel oxazole polyene γ-lactam/β-lactone antibiotic, is described. Key features include the stereocontrolled construction of the right-hand heterocyclic core bytaking advantage of an In(III)-cata

Total synthesis of neooxazolomycin

Two sides to the story: Neooxazolomycin, a member of the oxazolomycin family of antibiotics, was synthesized in naturally occurring form by a convergent approach. This highly stereoselective strategy consists of a Tamao hydrosilylation, palladium-catalyzed enolate alkenylation, dihydroxylation accompanied by lactonization, and a Nozaki-Hiyama-Kishi reaction to construct the right-hand segment as well as an improved route to the left-hand segment. (Chemical Equation Presented).