95599-69-2

Upstream product

• 85656-15-1 C₃₁H₃₈OSi 
• 80785-72-4 tetramesityldisilene 
• 50490-74-9 chloro-di-(2,4,6-trimethylphenyl)silane 
• 160011-52-9 dimesitylvinylfluorosilane 
• 160011-53-0 1,1-dimesitylneopentylsilene 
• 2633-66-1 2-mesitylmagnesium bromide 
• 120578-34-9 (2,4,6-trimethylphenyl)silane 
• 99798-82-0 bis(2,4,6-trimethyphenyl)silane 
• 119106-07-9 dimesitylfluorosilane 
• 576-83-0 2,4,6-trimethylphenyl bromide 

Downstream Products

• 1582790-19-9 C₇H₆N₂*C₁₈H₂₄O₂Si 

Relevant academic research and scientific papers

Silanediol hydrogen bonding activation of carbonyl compounds

Geo-inspired activation: The first example of silanediols activating amide and aldehyde substrates through hydrogen bonding is described. Both NMR and X-ray co-crystallization studies demonstrate binding modes and affinity, and show that silanediol hydrogen-bonding assemblies can be modulated by the addition of carbonyl compounds. These silanols show catalysis in a Diels-Alder reaction and provide insight into the design of new organocatalysts (see figure). Copyright

The electrochemistry of tetramesityldisilene, Mes2Si=SiMes2

The outcome of the controlled potential oxidation and reduction of a disilene, tetramesityldisilene (TMDS), indicates that the main silicon containing products involve only one silicon atom and have the general structure Mes2SiX(Y), X and Y being H, OH or F.

PHOTOSENSITIZED DECOMPOSITIONS OF OXASILACYCLOPROPANE; UNUSUAL CARBENE FORMATION

TCNE photo-sensitized decompositions of oxasilacyclopropane (1) generated carbene and silanone, while the DCA sensitized or direct photolysis of (1) gave silylene and indanone.