95599-85-2Relevant academic research and scientific papers
General Method for Generation of 3-Siloxyallylmetallic Species and Their Synthetic Application
Enda, Jun,Kuwajima, Isao
, p. 5495 - 5501 (2007/10/02)
On treatment with vinylmagnesium bromide, most of the α-branched acyltrimethylsilanes initially from the corresponding 1-(trimethylsilyl)allylic alkoxides, which undergo a facile rearrangement of the silyl group form carbon to oxygen to generate 3-(trimet
STOICHIOMETRIC GENERATION OF MAGNESIUM HOMOENOLATE EQUIVALENTS FROM ACYLTRIMETHYLSILANES. SYNTHESIS OF 1,6-DIKETONE DERIVATIVES
Enda, Jun,Matsutani, Tomohiro,Kuwajima, Isao
, p. 5307 - 5310 (2007/10/02)
Treatment of various acyltrimethylsilanes with vinylmagnesium bromide has allowed a stoichiometric generation of the corresponding 3-(trimethyl-siloxy)allylmagnesiums, which, in the presence copper(I) trimethylsilyl-acetylide, undergo conjugate addition t
