956015-86-4Relevant academic research and scientific papers
A thallium mediated route to σ-arylalkynyl complexes of bipyridyltricarbonylrhenium(I)
Liddle, Brendan J.,Lindeman, Sergey V.,Reger, Daniel L.,Gardinier, James R.
, p. 8484 - 8486 (2008/10/09)
A simple, one-pot preparation of rhenium(I) σ-arylalkynyl complexes is reported using thallium(I) hexafluorophosphate as a halogen abstraction agent. This new route to rhenium σ-alkynyls enjoys higher yields compared to analogous preparations using silver salts by eliminating potential electrochemical degradation pathways.
