95616-07-2Relevant academic research and scientific papers
Preparation and Thermal Ring Opening of 1-(Methylthio)cyclopropenes
Yoshida, Hiroshi,Sano, Hiroe,Kato, Makoto,Ogata, Tsuyoshi,Matsumoto, Kiyoshi
, p. 2833 - 2838 (2007/10/02)
The reaction of (methylthio)diphenyl- and methyl(methylthio)phenylcyclopropenium salts with Grignard reagents (methyl, 1-methylethyl, and phenyl) yielded 1-(methylthio)cyclopropenes as major products together with isomeric 3-methylthio-1-cyclopropenes in
An Extremely Facile Ring Opening of Substituted 1-(Alkylthio)cyclopropenes via Vinylcarbene Intermediates
Yoshida, Hiroshi,Kato, Makoto,Ogata, Tsuyoshi,Matsumoto, Kiyoshi
, p. 1145 - 1147 (2007/10/02)
Thermal ring opening of 1-(methylthio)cyclopropenes 2 takes place readily to give indene and/or butadiene derivatives in good yields, and product analysis of the reaction in methanol as well as kinetic studies of 2b gave strong evidence for the intermedia
