95616-79-8Relevant academic research and scientific papers
Preparation of new bis(dialkylamino)phosphine species via reduction of bis(dialkylamino)halophosphines
Snow, Sarah S.,Jiang, De-Xiang,Parry, Robert W.
, p. 1460 - 1463 (2008/10/08)
Four new bis(dialkylamino)phosphine species, (Me2N)2PH, CH3NCH2CH2N(CH3)PH, (CO)3Ni[(Me2N)2PH], and (CO)3Ni-[CH3NCH2CH2N(CH 3)PH], have easily been prepared in good yields through reduction of corresponding bis(dialkylamino)-halophosphines by lithium tri-sec-butylborohydride. The preparation and characterization of these compounds are discussed. An improved synthesis for obtaining quantitative yields of (CO)3NiL [L = Me2NPF2, (Me2N)2PF, CH3NCH2CH2N(CH3)PF] is also described.
