956315-04-1Relevant articles and documents
A fluorescent bicyclic calix[4]arene-oxacyclophane with planar chirality: Resolution, chiroptical properties, and absolute configuration
Prata, José V.,Costa, Alexandra I.,Pescitelli, Gennaro,Teixeira, Carlos M.
, p. 547 - 553 (2014)
A new inherently chiral calix[4]arene ICC 1 has been disclosed. The dissymmetry of 1 is generated from a chirality plane in the quinol moiety of a 1,3-bridged bicyclic calix[4]arene. ICC 1 has been resolved by enantioselective HPLC, and the chiroptical properties of both isolated antipodes (pS)-1 and (pR)-1 confirm their enantiomeric nature. The absolute configuration of the (pS)-1/(pR)-1 enantiomeric pair was established through time-dependent density functional theory (TDDFT) calculations of electronic circular dichroism (CD) spectra.
On/off electrochemical switches based on quinone-bisketals
Fuentes, Noelia,Cienfuegos, Luis Alvarez De,Parra, Andres,Choquesillo-Lazarte, Duane,Garcia-Ruiz, Juan M.,Marcos, M. Luisa,Bunuel, Elena,Ribagorda, Maria,Carreno, M. Carmen,Cardenas, Diego J.,Cuerva, Juan M.
supporting information; experimental part, p. 1586 - 1588 (2011/03/20)
The synthesis and anodic oxidation of a variety of 2,5-diaryl or dialkynylaryl substituted 1,4-dialkoxybenzenes to quinone bisketals is described. The study of the X-ray structures and electrochemical and spectroscopic properties evidenced that these pair