95634-16-5

Basic information

• Product Name: Carbamic acid, [5-amino-6-(ditetradecylamino)-6-oxohexyl]-, phenylmethyl ester, (S)-
• CAS NO: 95634-16-5
• Molecular Formula: C42H77N3O3
• Molecular Weight: 672.092
• Mol File: 95634-16-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Carbamic acid, [5-amino-6-(ditetradecylamino)-6-oxohexyl]-, phenylmethyl ester, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [5-amino-6-(ditetradecylamino)-6-oxohexyl]-, phenylmethyl ester, (S)-(95634-16-5)
• EPA Substance Registry System: Carbamic acid, [5-amino-6-(ditetradecylamino)-6-oxohexyl]-, phenylmethyl ester, (S)-(95634-16-5)

Safety Data

• Hazardous Substances Data: 95634-16-5(Hazardous Substances Data)

Upstream product

• 2389-45-9 Boc-Lys(Z)-OH 
• 17361-44-3 ditetradecylamine 
• 116058-81-2 ((S)-5-tert-Butoxycarbonylamino-5-ditetradecylcarbamoyl-pentyl)-carbamic acid benzyl ester 
• 2389-45-9 Nα-t-butoxycarbonyl-Nε-benzyloxycarbonyl-L-lysine 
• 116058-81-2 N,N-ditetradecyl-Nα-t-butoxycarbonyl-Nε-benzyloxycarbonyl-L-lysinamide 

Downstream Products

• 116058-83-4 N,N-ditetradecyl-Nα-<6-(trimethylammonio)hexanoyl>-Nε-benzyloxycarbonyl-L-lysinamide bromide 
• 116058-82-3 N,N-ditetradecyl-Nα-6-bromohexanoyl-Nε-benzyloxycarbonyl-L-lysinamide 

Relevant articles and documents

Syntheses of Macrocyclic Enzyme Models. Part 6. Preparation and Guest-Binding Behaviour of Octopus Cyclophanes

The following octopus cyclophanes constructed with a rigid macrocyclic skeleton and eight flexible hydrocarbon chains were prepared: N,N',N'',N'''-tetrakis(2-carbamoyl>ethyl)-3,10,21,28-tetraoxo-2,11,20,29-tetra-azaparacyclophane tetrachloride 2Lys2C14)4> and N,N',N'',N'''-tetrakispentan-5-yl>carbamoyl)ethyl>-3,10,21,28-tetraoxo-2,11,20,29-tetra-azaparacyclophane tetrabromide 2Lys(C5N+)2C14>4>.These host molecules provide cavities that are deep and hydrophobic enough to incorporate hydrophobic guests of various bulkiness through an induced-fit mechanism originating from the flexible character of the alkyl branhes.Both hydrophobic and electrostatic interactions come into effect in the host-guest complexation process, so that the molecular recognition is excercised by the preset hosts toward guests molecules.As regards the inclusion equilibrium between APC2Lys(C5N+)2C14>4 and pyrene, formation of both 1:2 and 1:1 (host:guest) complexes was remarkably favoured.The hydrophobic cage provided by the octopus cyclophane is highly apolar and acts to repress the molecular motion of guests; this was confirmed by fluorescene and fluorescence polarization spectroscopy, respectively.Both 2-azidobiphenyl and pyrene were simultaneously incorporated into the cyclophane cage as evidenced by kinetic analysis, and the pyrene-senzitized photolysis of the former species was enhanced under such conditions.The results imply that the octopus cyclophanes can be utilized as effective apoenzyme models for simulation of enzymatic functions.