95646-08-5Relevant articles and documents
Synthesis of chiral epoxy alcohols: Synthesis of (+)-disparlure
Kang, Suk-Ku,Kim, Yun-Sik,Lim, Jong-Suk,Kim, Kun-Soo,Kim, Sung-Gyu
, p. 363 - 366 (2007/10/02)
(2R,3S)-1,2-Epoxy alcohols 1, (2S,3S)-2,3-epoxy alcohols 2, and (2S,3S)-1,2-epoxy alcohols 3 were prepared from readily available (-)-2-deoxy-D-ribose. Using epoxy alcohol 3b as a chiral synthon, (+)-disparlure, the pheromone of the gypsy moth, Porthetria
STEREOSPECIFIC SYNTHESIS OF 11S,12S-OXIDO 5Z,7E,9E,14Z-EICOSATETRAENOIC ACID
Zamboni, Robert,Milette, Suzanne,Rokach, Joshua
, p. 5835 - 5838 (2007/10/02)
The first stereospecific synthesis of 11S,12S-oxido 5Z,7E,9E,14e-eicosatetraenoic acid has been achieved from 2-deoxy-D-ribose using either a Horner-Emmons or a Wittig condensation to form the 9,10-trans or the 5,6-cis-double bond respectively.